What characterizes a reversible process in thermodynamics?

Prepare for the ACS Physical Chemistry: Thermochemistry Test with detailed questions, flashcards, hints, and explanations. Get ready to excel in the exam!

A reversible process in thermodynamics is characterized by its ability to be reversed in such a manner that the system and surroundings can be returned to their original states without any net changes. This means that, in a reversible process, any change that occurs can be undone simply by making a very small change in the external conditions, such as pressure or temperature.

The statement about being able to reverse the process by an infinitesimal change in pressure emphasizes that reversible processes are conducted through a series of equilibrium states, allowing for a smooth transition back to the initial state. This characteristic is fundamental to the concept of reversibility, as it highlights the absence of dissipative forces that would usually result in energy losses.

While it is true that a reversible process ideally occurs without energy loss, which is often considered in thermodynamic discussions, the strongest distinguishing feature is the ability to reverse the process with minimal intervention. The production of no entropy change typically relates to the concept of idealized processes rather than defining reversibility, as real processes can result in positive entropy changes, but it is the approach to equilibrium that defines reversibility. Lastly, reversible processes do not necessarily occur at constant temperature; they can occur across a range of temperatures if the system approaches equilibrium continuously.

Thus, the

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