How is the chemical potential characterized throughout a system at equilibrium?

Prepare for the ACS Physical Chemistry: Thermochemistry Test with detailed questions, flashcards, hints, and explanations. Get ready to excel in the exam!

At equilibrium, the chemical potential of a system is characterized as uniform throughout the entire system. This means that the chemical potential, which is a measure of the potential energy of a species in a system due to its concentration and temperature, is the same at every point in a homogeneous system.

When a system reaches equilibrium, there is no net flow of particles in any direction, indicating that the driving forces for particle motion are balanced. If the chemical potential were not uniform, it would lead to a concentration gradient, and particles would tend to move from areas of higher chemical potential to areas of lower chemical potential until equilibrium is reached.

The concept of uniform chemical potential is crucial in understanding various thermodynamic processes and reactions, as it simplifies calculations and predictions about the behavior of the system. In scenarios where the chemical potential differs across the system, this indicates that the system is not at equilibrium, and changes will occur to bring the system to that state.

Thus, the chemical potential being uniform is a key characteristic of equilibrium, as it reflects stability and the absence of spontaneous changes within the system.

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